Synthesis and properties of trifluoroethoxy-coated binuclear phthalocyanine.
نویسندگان
چکیده
A genuine example of non-aggregated highly fluorescent binuclear phthalocyanines is reported; spectroscopic studies and computations revealed that the two halves of trifluoroethoxy-coated binuclear phthalocyanine are rotated in the same directions so as to contact each other as much as possible.
منابع مشابه
Synthesis of trifluoroethoxy-coated binuclear phthalocyanines with click spacers and investigation of their clamshell behaviour.
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We disclose herein the perfluoroalkylation of alkenes catalyzed by trifluoroethoxy-coated zinc phthalocyanine under irradiation of visible light. Perfluoroalkyl iodides were nicely incorporated into unsaturated substrates, including alkyne, to provide perfluoroalkyl and iodide adducts in moderate to good yields. Trifluoromethylation is also possible by trifluoromethyl iodide under the same reac...
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ورودعنوان ژورنال:
- Chemical communications
دوره 17 شماره
صفحات -
تاریخ انتشار 2008